J. C. Feng
,
M. Naka
,
J. C. Schuster(School of Materials Science and Engineering
,
Harbin Institute of Technology
,
Harbin
,
150001
,
China
,
Joining and Welding Research Institute
,
Osaka University
,
Mihogaoka 11 - 1
,
Ibaraki
,
Osaka 567
,
Japan
,
Institute of Physical Chemistry
,
University of Vienna
,
Austria )
金属学报(英文版)
Bonding of SiC to SiC using Ni and Ni - 25at%Cr foils was performed at high temperature.Interface structures and reaction phases were investigated by EPMA analyses and XRD diffraction method, re- spectively. At a bonding temperature of 1273K Ni reacts with SiC and forms various Ni silicides con- taining graphite baside SiC. Ni3Si without graphite was formed at Ni side.The interface structure of SiC/Ni joint was SiC/Ni2Si + C/Ni31 Si12 + G/Ni3 Si/Ni. At the interface between SiC and Ni- 25at%Cr alloy the Ni silicide was only Ni2Si at the same bonding temperature,and further(Cr, Ni)7 (Si, C)3 carbide was formed between Ni silicide + graphite zone and Ni - 25at%Cr alloy.The interface structure of SiC/Ni - 25at%Cr alloy was SiC/Ni2Si + C/(Cr, Ni)7 (Si, C)3+Ni(ss. Cr, Si)/Ni - 25at%Cr.
关键词:
interfacial structure
,
null
,
null
,
null
Xiaobing REN and Xiaotian WANG (College of Materials Science and Engineering
,
Xi'an Jiaotong University Xi'an 710049
,
China)K.Shimizu and T.Tadaki (Institute of Scientific and Industrial Research
,
Osaka University
,
8-1
,
Mihoga-oka
,
Ibaraki
,
Osaka
,
567
,
Ja
材料科学技术（英）
A theoretical study is developed on the evolution and mechanism of an ordering coupled phase separation, and on the origin of a resultant tweed microstructure. It is found that long-range elastic interaction among atoms with different atomic sizes plays a key role in the phase sep aration, and that the evolution of the phase separation is very similar to that Of conventional spinodal decomposition except that the separation is dependent on an elastic interaction order ing (EIO). This "EIO coupled spinodal decomposition" is shown to exhibit a periodical or tweed microstructure being accompanied by an EIO. It is also found that a large atomic size factor yields a large positive contribution of EIO to spinodal decomposition. Generally it is thermodynamically and kinetically favorable for the EIO to precede the onset of spinodal decomposition,though the former is not separable from the latter as a whole. We suggest that an initially disordered solid solution undergoes an EIO first, and then the partially ordered solid solution starts to decompose via a spinodal mechanism. Solute-enriched regions increase their degree of order along with an increase in solute content, and solute-depleted regions decrease their degree of order together with a decrease of solute content. The final microstructure is characterized by a periodical array of highly ordered solute-enriched regions and nearly disordered solute-depleted regions. The notion of EIO coupled spinodal decomposition is in general agreement with the transformation behaviour of a large number of alloy systems.
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